Paper

これまでの研究業績

原書論文

33. “Post-Synthetic Modification of Calix[4]arene Framework by Iridium–Mediated Alkyne Insertion into an Inert C−C Bond: A Novel Strategy for Unsymmetrical Macrocycles”
T. Iwamoto; H. Hasegawa; D. Mori; T. Yamazaki; K. Fujinuki; Y. Ishii
Chem. Eur. J. 2024, 30, e202401490

32. ”Vinylidene Rearrangements of Internal Borylalkynes via 1,2-Boryl Migration”
Dalton Trans. 2024, 53, 9715-9723
T. Iwamoto, T. Mitsubo, K. Sakajiri, Y. Ishii
Dalton Trans. 2024, 53, 9715-9723.

31. “One-pot Syntheses of Benzo- and Benzofuran-fused Iridaoxabenzenes via CH Bond Activations of Alkyl-bridged Diphenol Derivatives”
Iwamoto, T.*; Suzuki, M.; Hasegawa, H.; Abeta, H.; Matsuo, Y.; Tanaka, T.; Yasuda, N.; Ishii, Y.*
Chem. Asian. J. 2023, e202300640.

30. “Binuclear Complexes Supported by a Tetrapyridyl Ligand with a Bending Anthraquinodimethane Linker”
Iwamoto, T.*; Sotome, Y.; Ishii, Y.*
ACS Organic & Inorganic Au, 2023, 305–311.

29. “Retro-Vinylidene Rearrangements of P- and S-Substituted Ruthenium Vinylidene Complexes”
Iwamoto, T.*; Saito, K.; Mitsubo, T.; Kuwabara, T.; Ishii, Y.*
Organometallics 2023, 42, 167–173.

28. “Experimental Observation of β-Carbon Elimination from Alkenylrhodium Complexes through Exchange Reactions of the Alkenyl Unit”
Iwamoto, T.; Shibuya, K.; Takakuwa, T.; Kuwabara, T.; Ishii, Y.*
Organometallics 2022, 41, 182–186.

27. “Development of P- and N-Chirogenic Ligands Based on Chiral Induction from a Phosphorus Donor to a Nitrogen Donor in Palladium Complexes”
Iwamoto, T.*; Mizuhata, Y.; Tokitoh, N.; Nakamura, M.
Organometallics 2020, 39, 1672–1677.

26. “Endergonic Addition of N-Methylamines to Aromatic Ketones Driven by Photochemical Offset of the Entropic Cost”
Iwamoto, T.*; Hosokawa, A.; Nakamura, M.*
Chem. Commun. 2019, 55, 11683–11686.

25. “Iron-Catalysed Enantioselective Suzuki–Miyaura Coupling of Racemic Alkyl Bromides”
Iwamoto, T.; Okuzono, C.; Adak, L.; Jin, M.; Nakamura, M.*
Chem. Commun. 2019, 55, 1128–1131.

24. “Iron-Catalyzed Cross Coupling of Aryl Chlorides with Alkyl Grignard Reagents: Synthetic scope and FeII/FeIV mechanism supported by X-ray absorption spectroscopy and density functional theory calculations”
Agata, R.; Takaya, H.; Matsuda, H.; Nakatani, N.; Takeuchi, K.; Iwamoto, T.; Hatakeyama, T.; Nakamura, M.*
Bull. Chem. Soc. Jpn. 2019, 92, 381–390.

23. “DFT and AFIR Study on the Mechanism and the Origin of Enantioselectivity in Iron-Catalyzed Cross-Coupling Reactions”
Sharma, A. K.; Sameera, W. M. C.; Jin, M.; Adak, L.; Okuzono, C.; Iwamoto, T.; Kato, M.; Nakamura, M.; Morokuma, K.
J. Am. Chem. Soc. 2017, 139, 16117–16125.

22. ” Iron-Catalyzed anti-Selective Carbosilylation of Internal Alkynes”
Iwamoto, T.; Nishikori, T.; Nakagawa, N.; Takaya, H.; Nakamura, M.*
Angew. Chem. Int. Ed. 2017, 56, 13298–13301.

21. ”Shortest Double-Walled Carbon Nanotubes Composed of Cycloparaphenylenes”
Hashimoto, S.; Iwamoto, T.; Kurachi, D.; Kayahara, E.; Yamago, S.*
ChemPlusChem 2017, 82, 1015–1020.

20. “ONO-pincer ruthenium complex-bound norvaline for efficient catalytic oxidation of methoxybenzenes with hydrogen peroxide”
Yoshida, R.; Isozaki, K.; Yokoi, T.; Yasuda, N.; Sadakane, K; Iwamoto, T.; Takaya, H.; Nakamura. M.
Org. Biomol. Chem. 2016, 14, 7468–7479.

19. “Ligand-controlled Synthesis of [3]- and [4]Cyclo-9,9-dimethyl-2,7-fluorenes through Triangle- and Square-shaped Platinum Intermediates”
Kayahara, E; Qu, R.; Kojima, M.; Iwamoto, T.; Suzuki, T.; Yamago, S.*
Chem. Eur. J. 2015, 21, 18939–18943.

18. “Radical Ions of Cyclopyrenylene: Comparison of Spectral Properties with Cycloparaphenylene.”
Fujistuka, M.; Tojo, S.; Iwamoto, T.; Kayahara, E.; Yamago, S.; Majima, T.
J. Phys. Chem. Part A 2015, 119, 4136–4141.

17. “Iron(III) Fluoride/N-Heterocyclic Carbene Catalyzed Cross Coupling between Deactivated Aryl Chlorides and Alkyl Grignard Reagents with or without b-Hydrogens”
Agata, R.; Iwamoto, T.; Nakagawa, N.; Isozaki, K.; Hatakeyama, T.; Takaya, H.; Nakamura. M.*
Synthesis 2015, 47, 1733–1740.

16. “Investigation of Organoiron Catalysis in Kumada–Tamao–Corriu-Type Cross-Coupling Reaction Assisted by Solution-Phase X-ray Absorption Spectroscopy”
Takaya, H.; Nakajima, S.; Nakagawa, N.; Isozaki, K.; Iwamoto, T.; Imayoshi, R.; Gower, N. J.; Adak, L.; Hatakeyama, T.; Honma, T.; Takagaki, M.; Sunada, Y.; Nagashima, H.; Hashizume, D.; Takahashi, O.; Nakamura. M.*
Bull. Chem. Soc. J. 2015, 20, 14403–14409.

15. “Partial Charge Transfer in Shortest Possible Metallofullerene Peapod, La@C82⸦[11]Cycloparaphenylene.”
Iwamoto, T.; Slanina, Z.; Mizorogi, N.; Guo, J.; Akasaka, T.; Nagase, S.; Takaya, H.; Yasuda, N.; Kato, T.; Yamago, S.*
Chem. Eur. J. 2014, 20, 14403–14409.

14. “Chameleon-like Behaviour of Cyclo[n]paraphenylenes in Complexes with C70. On Their Impressive Electronic and Structural Adaptability as probed By Raman spectroscopy.”
PeñaAlvarez, M.; Burrezob, P. M.; Iwamoto, T.; Taravilloa, M.; Baonzaa, V. G.; Navarreteb, J. T. L.; Yamago, S.; Casado, J.*
Faraday Discussion 2014, 173, 157–171.

13. “Radical Ions of Cycloparaphenylenes: Size-Dependence Contrary to the Neutral Molecules”
Fujitsuka, M.; Tojo, S.; Iwamoto, T.; Kayahara, E.; Yamago, S.; Majima, T.
J. Phys. Chem. Lett. 2014, 5, 2302–2305.

12. “Properties of Triplet-Excited [n]Cycloparaphenylenes (n = 8-12): Excitation Energies Lower than Those of Linear Oligomers and Polymers”
Fujitsuka, M.; Lu, C.; Iwamoto, T.; Kayahara, E.; Yamago, S.; Majima, T.
J. Phys. Chem. A 2014, 118, 4527–4532.

11. “Synthesis, Characterization, and Properties of [4]Cyclo-2,7-pyrenylene: Effect of Cyclic Structure on the Electronic Properties of Pyrene Oligomers”
Iwamoto, T.; Kayahara, E.; Yasuda, N.; Suzuki, T.; Yamago, S.*
Angew. Chem. Int. Ed. 2014, 53, 6430–6434.

10. “Properties of Sizeable [n]Cycloparaphenylenes as Molecular Models of Single-Wall Carbon Nanotubes Elucidated by Raman Spectroscopy: Structural and Electron-Transfer Responses under Mechanical Stress”
Alvarez, M. P.; Burrezo, P. M.; Kertesz, M.; Iwamoto, T.; Yamago, S.; Xia, J.; Jasti, R.; Navarrete, J. T. L.; Taravillo, M.; Baonza, V. G.; Casado, J.*
Angew. Chem. Int. Ed. 2014, 53, 7033–7037.

9. “Electron Transfer in a Supramolecular Associate of a Fullerene Fragment”
Gallego, M.; Calbo, J.; Aragó, , J.; Krick Calderon, R. M.; Liquido, F. H.; Iwamoto, T.; Greene, A. K.; Jackson, E. A.; Pérez, E. M.; Ortí, E.; Guldi, D. M.; Scott, L. T.; Martín, N.*
Angew. Chem. Int. Ed. 2014, 53, 2170–2175.

8. “Synthesis and Physical Properties of a Ball-Like Three-Dimensional -Conjugated Molecule”
Kayahara, E.; Iwamoto, T.; Takaya, H.; Suzuki, T.; Fujitsuka, M.; Majima, T.; Yasuda, N.; Matsuyama, N.; Seki, S.; Yamago, S.*
Nature Commun. 2013, 4, 2694.

7. “Size- and Orientation-Selective Encapsulation of C70 by Cycloparaphenylenes”
Iwamoto, T.; Watanabe, Y.; Takaya, H.; Haino, T.; Yasuda, N.; Yamago, S.*
Chem. Eur. J. 2013, 19, 14061–14068.

6. “Selective Synthesis of [6]-, [8]-, and [10]Cycloparaphenylenes”
Kayahara, E.; Iwamoto, T.; Suzuki, T.; Yamago, S.*
Chem. Lett. 2013, 42, 621–623.

5. “Enhancement of Quinoidal Character of Smaller [n]Cycloparaphenylenes Probed by Raman Spectroscopy”
Fujitsuka, M.; Iwamoto, T.; Kayahara, E.; Yamago, S.; Majima, T.
ChemPhysChem. 2013, 14, 1570–1572.

4. “Size-Dependent Fluorescence Properties of [n]Cycloparaphenylenes (n =8-13), Hoop-Shaped π-Conjugated Molecules”
Fujitsuka, M.; Cho, D. W.; Iwamoto, T.; Yamago, S.; Majima, T.
Phys. Chem. Chem. Phys. 2012, 14, 14585–14588.

3. “Size-Selective Encapsulation of C60 by [10]Cycloparaphenylene: Formation of the Shortest Fullerene-Peapod”
Iwamoto, T.; Watanabe, Y.; Sadahiro, T.; Haino, T.; Yamago, S.*
Angew. Chem. Int. Ed. 2011, 50, 8342–8344.

2. “Selective and Random Syntheses of [n]Cycloparaphenylenes (n = 8-13) and Size Dependence of Their Electronic Properties”
Iwamoto, T.; Watanabe, Y.; Sakamoto, Y.; Suzuki, T.; Yamago, S.*
J. Am. Chem. Soc. 2011, 133, 8354–8361.

1. “Synthesis of [8]Cycloparaphenylene from a Square-Shaped Tetranuclear Platinum Complex”
Yamago, S.*; Watanabe, Y.; Iwamoto, T.
Angew. Chem. Int. Ed. 2010, 49, 757–759.

総説、解説記事

8. “Vinylidene Complexes”　
Iwamoto, T.; Ishii, Y.
Encyclopedia of Inorganic and Bioorganic Chemistry, 2022.

7. “Iron-Catalyzed Enantioselective Cross-Coupling Reactions for the Synthesis of Propionic Acid Anti-inflammatory Compounds”
Nakamura, M.; Iwamoto, T.; Jin, M.; Okuzono, C.
Chemical Times, 2021, 1, 13–19.

5. “Metalated Amino Acids and Peptides: A Key Functional Platform for Applications to Controlled Metal Array Fabrication and Supramolecular Catalysts”
Takaya, H.; Isozaki, K.; Yokoi, T.; Ogata, K.; Shanoh, T.; Yasuda, N.; Iwamoto, T.; Nakamura, M.
Journal of Synthetic Organic Chemistry Japan 2019, 76, 1010–1023.

4. 「光触媒が拓く炭素資源の分子変換-二酸化炭素の一電子還元を起点とするカルボキシル化反応」
化学、2018, 73, 70–71.　化学同人

3. “Organoplatinum-Mediated Synthesis of Cyclic π-Conjugated Molecules: Towards a New Era of Three-Dimensional Aromatic Compounds”
Yamago, S.; Kayahara, E.; Iwamoto, T.
Chem. Rec. 2014, 14, 84–100.

2. “Structural Investigation of Cycloparaphenylene –Fullerene Supramolecular Complexes Using Synchrotron Radiation and Theoretical Calculation”
Iwamoto, T.; Takaya, H.; Yamago, S.
Nihon Kessho Gakkaishi, 2015, 57, 239–244.

1. “New Organic Chemistry of Three-Dimensional π-Conjugated Compounds”
Yamago, S.; Kayahara, E.; Iwamoto, T.
Journal of Synthetic Organic Chemistry, Japan. 2014, 72, 992-1005.